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| Abstract
The purpose of this paper is to offer an introductory
treatment of the differential equation the Schrodinger wave equation.
For the sake of both brevity and simplicity, only the time-independent
wave equation in one-dimension will be considered. By way of this,
the historical developments that gave rise to this equation that is so
integral to quantum physics will be addressed. Further, to illustrate
the equation, the particle in a rigid box model is examined.
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As the dawn of a new century approached, physics was intoxicated with what the ancient Greeks wisely called hubris -- false, insolent, destructive pride. Indeed, as a young man eager to pursue physics, Max Planck was advised by the head of the physics department at Munich "The important discoveries [in physics] have been made. It is hardly worth entering physics anymore (Kotz and Treichel, 320)." Fortunately, this advise he did not heed. Classical physics -- that is, Newtonian mechanics and Maxwell's theory of electromagnetism -- seemingly accounted for all observed natural phenomena. It was a deterministic universe. The planets, eternally whirling with their inscrutable precision; the ebbing and flowing of the sea's tides; the oscillations of a pendulum; the way bodies exchange energy and momentum; waves of light propagating through space -- do they all not obey a deterministic model? Some claimed that given the initial conditions of the universe, all of its future behavior could calculated.
Alas, as so often occurs in science, a crisis arose that was fatal in nature to classical physics: it failed to account for certain important phenomena. This was the ultraviolet catastrophe, and standing at the center of it was the man who had been discouraged from pursuing physics because all but the minor details had been worked out, Max Planck.
An ideal object that absorbs all radiation incident upon it is known as a blackbody. A reasonable approximation may be made by employing a cavity that has a very small aperture. Only a negligible amount of radiation entering the cavity escapes. The characteristic energy radiation of a blackbody -- ergo, the name -- is not visible, but rather in the infrared region of the electromagnetic spectrum. In classical physics, the spectral distribution function is given by the Raleigh-Jeans law,
where l is the wavelength, T is the temperature, and k is the Boltzmann constant. The agreement between the predicted values and observed was excellent for large wavelengths. However, as l approaches zero, it is predicted it would radiate an infinite amount of energy of extremely small wavelengths, the ultraviolet region.
Tacit in this model is that radiation, such as visible light, propagates through space and exchanges energy as a wave. That is, it is continuous, non-localized, spread out. Newton had argued that it is transmitted in discrete particles called corpuscles. However, later experiments with interference and diffraction seemed to indicate it was a wave.
Planck's approach was to alter the model.
For the the sake of developing an accurate model, and only for the sake
of accurate model, assume that energy emitted or absorbed by a blackbody
came in discrete units, or quanta, like particles. He even
determined the relationship by which the energy is quantized:
| E=nhf |
The energy is given by some integer, n, multiplied by Planck's constant, h, and the frequency, f, of the radiation. However, he insisted this was not the way nature actually behaved, merely a model. Indeed, some years later when Einstein used this principle to explain the photoelectric effect, Planck questioned the veracity of the argument. Eventually, as did the whole of the scientific community, he came around and realized the implications.
Though he did not initially appreciate it,
he had open the door for a new paradigm that would assert itself with such
vigor that virtually no field of science would be left untouched by it:
quantum physics. In particular, he had stumbled into
the thorny briar of wave-particle duality. Light seems to
propagate like a wave and exchange energy like a particle. Einstein
commented on the counterintuitive nature of this dichotomy saying
| All the fifty years of conscious brooding have brought me no closer to the answer to the question, "what are light quanta?" Of course today every rascal thinks he knows the answer, but he is deluding himself (Knight, 442). |
One such neophyte was a french prince and graduate
student in physics, Louis-Victor DeBroglie. Suppose the concept of
the light quanta of Planck and Einstein is broadened. What if it
is not merely light that exhibits both wave and particle properties?
What if an electron or a proton or a atom or a baseball or a planet exhibits
them? And what does this tell us of the nature of matter? DeBroglie's
answer was that, indeed, wave-particle duality is not limited to just light.
All objects, microscopic and macroscopic, display it. He postulated
that the wavelength of these so-called matter waves is given by
where h is, once again, Planck's constant, p is momentum, m is mass, and v is velocity.
This postulate was quickly confirmed using x-ray crystallography to examine
the behavior of electrons. As may be seen in the adjacent illustration,
electrons exhibit a diffraction pattern that is characteristic of waves.
That is, as they propagate, they interfere with one another, yet it is
known that they are indeed discrete units or particles. Interference
may only occur if they also possess wave properties. Therefore, matter
-- not only light -- propogates as waves and exchanges energy as particles.
The troubling dichotomy of waves and particle of light quanta cannot be
escaped. It is replete throughout nature: in packets of light quanta,
photons; in subatomic particles such as electrons and protons; in the flight
of a baseball; in the orbit of a planet. However, the wavelength
for macroscopic objects, such as baseballs and planets, is so small
as to be virtually undetectable.